| Services |
|
|
|
|
 |
|
| News |
|
|
|
|
|
|
|
|
|
| Channels |
| Home & Family |
|
|
|
|
|
|
|
| Leisure |
|
|
|
|
| Technology |
|
|
|
|
|
| Business |
|
|
|
|
| Science |
|
|
|
|
|
|
|
|
|
|
Site Search  |
|
|
|
|
| Free email |
|
|
|
|
 |
Scientists resolve 60-year-old plutonium questions |
| TheAllINeed.com/NC&T/LLNL/ |
Plutonium behaves like no other element in nature. The bonding of its electrons causes its crystal structure to be uneven, similar to a mineral, and the nucleus is unstable, causing the metal to spontaneously decay over time and damage the surrounding metal lattice.
First batches of the metal were too brittle to machine due to the mineral-like structure of the crystal. In order to make the metal machinable, the high-temperature, high-symmetry cubic structure of plutonium needed to be retained to room temperature.
Scientists during the Manhattan Project achieved this by adding a small amount of gallium.
"There was never a clear explanation as to why gallium stabilized the ductile cubic structure over the low-symmetry mineral-like structure; they just did it and it worked," said Kevin Moore, a staff scientist in the Materials Science and Technology Division at Lawrence Livermore National Laboratory.
For the first time, researchers have determined why gallium works. In pure plutonium, the bonds between Pu atoms are very uneven, causing the metal's high propensity to adopt a low-symmetry structure. However, when a gallium atom is put in the plutonium lattice, it causes the bonds to become more uniform and thus leads to the high-symmetry cubic structure.
"Gallium evens out the plutonium bonds," Moore said. "The calculations strongly illuminate why gallium stabilizes the machinable cubic structure to room temperature.
 | | A plutonium-gallium alloy ingot reclaimed from a nuclear weapon (Photo: LLNL) |
"Previous experiments tell us that the plutonium lattice distorts as it ages, but there was no clear explanation as to why this happens," said Moore, an experimentalist by training. "Our calculations explain the observations, showing the distortions are the response of plutonium and its uneven bonds to having defects produced in the crystal due to self irradiation. These calculations further our confidence in the safety, security and reliability of aging plutonium in stockpile warheads."
Through a series of calculations, Moore and his Livermore colleagues, Per Söderlind and Adam Schwartz, and David Laughlin of Carnegie Mellon University have produced results that appear in the May 26 online edition of Physical Review Letters.
The team next proposes to test their calculations in the laboratory.
|
| About the Author |
ICRC ©2006 All rights reserved
|
|
|
| Quotes | Have you seen a tall, lanky dufus with a bird face and hair like the bride of Frankenstein?-Elaine, describing Kramer
Having major planets disappear is always a bad sign.- Jim Blinn
Great minds have purposes, others have wishes.- Washington Irving
Great spirits often meet violent opposition with mediocre minds - Albert Einstein
|
| Writers | | If you are a writer and want to see your article published at Theallineed.com, just click here to submit. |
|
Top UN officials call for release of Daw Aung San Suu Kyi
Buyer beware: bed bugs can squash real estate deals